TITLE 35: ENVIRONMENTAL PROTECTION
SUBTITLE G: WASTE DISPOSAL CHAPTER I: POLLUTION CONTROL BOARD SUBCHAPTER c: HAZARDOUS WASTE OPERATING REQUIREMENTS
PART 728
LAND DISPOSAL RESTRICTIONS
SECTION 728.TABLE F ALTERNATIVE TREATMENT STANDARDS FOR HAZARDOUS DEBRIS
Section 728.TABLE F Alternative
Treatment Standards For Hazardous Debris
a) Hazardous debris must be treated by either the standards
indicated in this Table F or by the waste-specific treatment standards for the
waste contaminating the debris. The treatment standards must be met for each
type of debris contained in a mixture of debris types, unless the debris is
converted into treatment residue as a result of the treatment process. Debris
treatment residuals are subject to the waste-specific treatment standards for
the waste contaminating the debris.
b) Definitions. For the purposes of this Table F, the following
terms are defined as follows:
"Clean
debris surface" means the surface, when viewed without magnification, must
be free of all visible contaminated soil and hazardous waste except that
residual staining from soil and waste consisting of light shadows, slight
streaks, or minor discolorations, and soil and waste in cracks, crevices, and
pits may be present provided that such staining and waste and soil in cracks,
crevices, and pits must be limited to no more than five percent of each square
inch of surface area.
"Contaminant
restriction" means that the technology is not BDAT for that contaminant.
If debris containing a restricted contaminant is treated by the technology, the
contaminant must be subsequently treated by a technology for which it is not
restricted in order to be land disposed (and excluded from Subtitle C
regulation).
"Dioxin-listed
wastes" means wastes having any of USEPA hazardous waste numbers FO20,
FO21, FO22, FO23, FO26, or FO27.
c) Notes. In this Table F, the following text is to be read in
conjunction with the tabulated text where the appropriate notations appear:
1 Acids,
solvents, and chemical reagents may react with some debris and contaminants to
form hazardous compounds. For example, acid washing of cyanide-contaminated
debris could result in the formation of hydrogen cyanide. Some acids may also
react violently with some debris and contaminants, depending on the
concentration of the acid and the type of debris and contaminants. Debris
treaters should refer to the safety precautions specified in Material Safety
Data Sheets for various acids to avoid applying an incompatible acid to a
particular debris/contaminant combination. For example, concentrated sulfuric
acid may react violently with certain organic compounds, such as acrylonitrile.
2
If reducing the particle size of debris to meet the treatment standards results
in material that no longer meets the 60 mm minimum particle size limit for
debris, such material is subject to the waste-specific treatment standards for
the waste contaminating the material, unless the debris has been cleaned and
separated from contaminated soil and waste prior to size reduction. At a
minimum, simple physical or mechanical means must be used to provide such
cleaning and separation of nondebris materials to ensure that the debris surface
is free of caked soil, waste, or other nondebris material.
3
Thermal desorption is distinguished from thermal destruction in that the
primary purpose of thermal desorption is to volatilize contaminants and to
remove them from the treatment chamber for subsequent destruction or other
treatment.
4
The demonstration of "equivalent technology" pursuant to Section
728.142(b) must document that the technology treats contaminants subject to
treatment to a level equivalent to that required by the performance and design
and operating standards for other technologies in this table such that residual
levels of hazardous contaminants will not pose a hazard to human health and the
environment absent management controls.
5
Any soil, waste, and other nondebris material that remains on the debris
surface (or remains mixed with the debris) after treatment is considered a
treatment residual that must be separated from the debris using, at a minimum,
simple physical or mechanical means. Examples of simple physical or mechanical
means are vibratory or trommel screening or water washing. The debris surface
need not be cleaned to a "clean debris surface" as defined in
subsection (b) when separating treated debris from residue; rather, the surface
must be free of caked soil, waste, or other nondebris material. Treatment
residuals are subject to the waste-specific treatment standards for the waste
contaminating the debris.
Technology Description
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Performance or Design
and Operating Standard
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Contaminant Restrictions
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A. Extraction
Technologies:
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1. Physical
Extraction
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a. Abrasive
Blasting: Removal of contaminated debris surface layers using water or air
pressure to propel a solid media (e.g., steel shot, aluminum oxide grit, plastic
beads).
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Glass, Metal, Plastic,
Rubber: Treatment to a clean debris surface.
Brick, Cloth,
Concrete, Paper, Pavement, Rock, Wood: Removal of at least 0.6 cm of the
surface layer; treatment to a clean debris surface.
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All Debris: None.
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b. Scarification,
Grinding, and Planing: Process utilizing striking piston heads, saws, or
rotating grinding wheels such that contaminated debris surface layers are
removed.
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Same as above
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Same as above
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c. Spalling: Drilling
or chipping holes at appropriate locations and depth in the contaminated
debris surface and applying a tool that exerts a force on the sides of those
holes such that the surface layer is removed. The surface layer removed
remains hazardous debris subject to the debris treatment standards.
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Same as above
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Same as above
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d. Vibratory
Finishing: Process utilizing scrubbing media, flushing fluid, and
oscillating energy such that hazardous contaminants or contaminated debris
surface layers are removed.1
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Same as above
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Same as above
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e. High Pressure
Steam and Water Sprays: Application of water or steam sprays of sufficient
temperature, pressure, residence time, agitation, surfactants, and detergents
to remove hazardous contaminants from debris surfaces or to remove
contaminated debris surface layers
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Same as above
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Same as above.
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2. Chemical
Extraction
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a. Water Washing and
Spraying: Application of water sprays or water baths of sufficient
temperature, pressure, residence time, agitation, surfactants, acids, bases,
and detergents to remove hazardous contaminants from debris surfaces and
surface pores or to remove contaminated debris surface layers.
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All Debris: Treatment
to a clean debris surface; Brick, Cloth, Concrete, Paper, Pavement, Rock,
Wood: Debris must be no more than 1.2 cm (½ inch) in one dimension (i.e.,
thickness limit,2 except that this thickness limit may be waived
under an "Equivalent Technology" approval pursuant to Section 728.142(b);4
debris surfaces must be in contact with water solution for at least 15
minutes
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Brick, Cloth,
Concrete, Paper, Pavement, Rock, Wood: Contaminant must be soluble to at
least five percent by weight in water solution or five percent by weight in
emulsion; if debris is contaminated with a dioxin-listed waste,3
an "Equivalent Technology" approval pursuant to Section 728.142(b)
must be obtained.4
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b. Liquid Phase
Solvent Extraction: Removal of hazardous contaminants from debris surfaces
and surface pores by applying a nonaqueous liquid or liquid solution that causes
the hazardous contaminants to enter the liquid phase and be flushed away from
the debris along with the liquid or liquid solution while using appropriate
agitation, temperature, and residence time.1
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Same as above
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Brick, Cloth,
Concrete, Paper, Pavement, Rock, Wood: Same as above, except that contaminant
must be soluble to at least five percent by weight in the solvent.
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c. Vapor Phase
Solvent Extraction: Application of an organic vapor using sufficient
agitation, residence time, and temperature to cause hazardous contaminants on
contaminated debris surfaces and surface pores to enter the vapor phase and
be flushed away with the organic vapor.1
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Same as above, except
that brick, cloth, concrete, paper, pavement, rock and wood surfaces must be
in contact with the organic vapor for at least 60 minutes.
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Same as above.
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3. Thermal Extraction
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a. High Temperature
Metals Recovery: Application of sufficient heat, residence time, mixing,
fluxing agents, or carbon in a smelting, melting, or refining furnace to
separate metals from debris.
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For refining furnaces,
treated debris must be separated from treatment residuals using simple
physical or mechanical means,5 and, prior to further treatment,
such residuals must meet the waste-specific treatment standards for organic
compounds in the waste contaminating the debris.
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Debris contaminated
with a dioxin-listed waste:2 Obtain an "Equivalent Technology"
approval pursuant to Section 728.142(b).4
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b. Thermal
Desorption: Heating in an enclosed chamber under either oxidizing or
nonoxidizing atmospheres at sufficient temperature and residence time to
vaporize hazardous contaminants from contaminated surfaces and surface pores
and to remove the contaminants from the heating chamber in a gaseous exhaust
gas.3
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All Debris: Obtain an "Equivalent
Technology" approval pursuant to Section 728.142(b);4 treated
debris must be separated from treatment residuals using simple physical or
mechanical means,5 and, prior to further treatment, such residue
must meet the waste-specific treatment standards for organic compounds in the
waste contaminating the debris.
Brick, Cloth,
Concrete, Paper, Pavement, Rock, Wood: Debris must be no more than 10 cm (4
inches) in one dimension (i.e., thickness limit),2 except that
this thickness limit may be waived under the "Equivalent Technology"
approval
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All Debris: Metals other
than mercury.
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B. Destruction
Technologies
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1. Biological
Destruction (Biodegradation): Removal of hazardous contaminants from debris
surfaces and surface pores in an aqueous solution and biodegradation of
organic or nonmetallic inorganic compounds (i.e., inorganics that contain
phosphorus, nitrogen, or sulfur) in units operated under either aerobic or
anaerobic conditions.
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All Debris: Obtain an "Equivalent
Technology" approval pursuant to Section 728.142(b);4 treated
debris must be separated from treatment residuals using simple physical or
mechanical means,5 and, prior to further treatment, such residue
must meet the waste-specific treatment standards for organic compounds in the
waste contaminating the debris.
Brick, Cloth,
Concrete, Paper, Pavement, Rock, Wood: Debris must be no more than 1.2 cm (½
inch) in one dimension (i.e., thickness limit),2 except that this
thickness limit may be waived under the "Equivalent Technology"
approval
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All Debris: Metal
contaminants.
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2. Chemical
Destruction
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a. Chemical
Oxidation: Chemical or electrolytic oxidation utilizing the following oxidation
reagents (or waste reagents) or combination of reagents: (1) hypochlorite
(e.g., bleach); (2) chlorine; (3) chlorine dioxide; (4) ozone or UV
(ultraviolet light) assisted ozone; (5) peroxides; (6) persulfates; (7)
perchlorates; (8) permanganates; or (9) other oxidizing reagents of
equivalent destruction efficiency.1 Chemical oxidation
specifically includes what is referred to as alkaline chlorination.
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All Debris: Obtain an "Equivalent
Technology" approval pursuant to 35 Ill. Adm. Code.142(b);4
treated debris must be separated from treatment residuals using simple
physical or mechanical means,5 and, prior to further treatment,
such residue must meet the waste-specific treatment standards for organic
compounds in the waste contaminating the debris.
Brick, Cloth,
Concrete, Paper, Pavement, Rock, Wood: Debris must be no more than 1.2 cm (½
inch) in one dimension (i.e., thickness limit),2 except that this
thickness limit may be waived under the "Equivalent Technology"
approval
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All Debris: Metal contaminants.
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b. Chemical
Reduction: Chemical reaction utilizing the following reducing reagents (or
waste reagents) or combination of reagents: (1) sulfur dioxide; (2) sodium,
potassium, or alkali salts of sulfites, bisulfites, and metabisulfites, and
polyethylene glycols (e.g., NaPEG and KPEG); (3) sodium hydrosulfide; (4)
ferrous salts; or (5) other reducing reagents of equivalent efficiency.1
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Same as above
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Same as above.
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3. Thermal
Destruction: Treatment in an incinerator operating in accordance with Subpart
O of 35 Ill. Adm. Code 724 or Subpart O of 35 Ill. Adm. Code 725; a boiler or
industrial furnace operating in accordance with Subpart H of 35 Ill. Adm.
Code 726, or other thermal treatment unit operated in accordance with Subpart
X of 35 Ill. Adm. Code 724, or Subpart P of 35 Ill. Adm. Code 725, but
excluding for purposes of these debris treatment standards Thermal Desorption
units.
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Treated debris must be
separated from treatment residuals using simple physical or mechanical means,5
and, prior to further treatment, such residue must meet the waste-specific
treatment standards for organic compounds in the waste contaminating the
debris.
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Brick, Concrete,
Glass, Metal, Pavement, Rock, Metal: Metals other than mercury, except that
there are no metal restrictions for vitrification.
Debris contaminated
with a dioxin-listed waste.3 Obtain an "Equivalent Technology"
approval pursuant to Section 728.142(b),4 except that this
requirement does not apply to vitrification.
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C. Immobilization
Technologies
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1. Macroencapsulation:
Application of surface coating materials such as polymeric organics (e.g.,
resins and plastics) or use of a jacket of inert inorganic materials to
substantially reduce surface exposure to potential leaching media.
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Encapsulating material
must completely encapsulate debris and be resistant to degradation by the
debris and its contaminants and materials into which it may come into contact
after placement (leachate, other waste, microbes).
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None.
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2. Microencapsulation:
Stabilization of the debris with the following reagents (or waste reagents)
such that the leachability of the hazardous contaminants is reduced: (1)
Portland cement; or (2) lime/ pozzolans (e.g., fly ash and cement kiln
dust). Reagents (e.g., iron salts, silicates, and clays) may be added to
enhance the set/cure time or compressive strength, or to reduce the
leachability of the hazardous constituents.2
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Leachability of the
hazardous contaminants must be reduced.
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None.
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3. Sealing:
Application of an appropriate material that adheres tightly to the debris
surface to avoid exposure of the surface to potential leaching media. When
necessary to effectively seal the surface, sealing entails pretreatment of
the debris surface to remove foreign matter and to clean and roughen the
surface. Sealing materials include epoxy, silicone, and urethane compounds,
but paint may not be used as a sealant
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Sealing must avoid
exposure of the debris surface to potential leaching media and sealant must
be resistant to degradation by the debris and its contaminants and materials
into which it may come into contact after placement (leachate, other waste,
microbes).
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None.
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BOARD NOTE: Derived
from Table 1 to 40 CFR 268.45 (2017).
(Source: Amended at 42 Ill.
Reg. 24924, effective November 19, 2018)
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